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In a still further particular aspect the indication is (iii)

1b): 7,8,9,10,11,12,15,17,19,30 During the oxidative half-reaction the thiolate group of the reduced glutaredoxin attacks the GSSR disulfide bond, yielding the first product (RSH) and the glutathionylated glutaredoxin Grx(SSG) as an intermediate

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Formate Metabolism: formyl coenzyme A, an intermediate in the formate-dependent decomposition of acetyl phosphate in Clostridium kluyveri