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Further structural optimization delivered a large number of macrocyclic disulfides and among them 23 (HA08) encompassing a 3-homotyrosine residue in a 13-membered ring system and exhibiting the lowest Ki value in the series (Ki = 3.3 nM)
103 Activation of histone deacetylase Sirtuin1 (SIRT1) promotes ferroptosis in HNC cells, increases ZEB1 expression, and decreases E-cadherin levels
PARP cleavage inhibition: PARP, a downstream target of caspase-3, saw its cleavage fragments reduced by 77.5%
